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Kinetics and Mechanism of the Formation of Ylides, 1, 4 or 1, 5-Diionic Organophosphorus and Phosphonate Esters: A Review

[ Vol. 16 , Issue. 1 ]

Author(s):

Sayyed Mostafa Habibi-Khorassani*, Mehdi Shahraki and Bahareh Mostafa   Pages 59 - 77 ( 19 )

Abstract:


The kinetics and mechanism of the formation of some ylides,1,4 or 1,5-diionic organophosphorus and phosphonate esters have been reviewed. The UV-vis spectrophotometry, stopped-flow and variable-temperature 1H-NMR spectroscopy along with the theoretical calculations were used as investigative techniques.

Keywords:

NMR techniques, kinetics, mechanism, ylides, phosphonate esters, diionic organophosphorus.

Affiliation:

Sayyed Mostafa Habibi-Khorassani Department of ChemistryFaculty of ScienceUniversity of Sistan and Baluchestan, Zahedan , Department of ChemistryFaculty of ScienceUniversity of Sistan and BaluchestanZahedan, Iran - Stopped-Flow, Kinetics, Theoretical chemistry, Zahedan, University of Sistan and Baluchestan - Chemistry, Zahedan



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