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Aryl-Aryl Bond Formation by Ullmann Reaction: From Mechanistic Aspects to Catalyst

[ Vol. 17 , Issue. 1 ]

Author(s):

Jie Jiang, Liyong Du and Yuqiang Ding*   Pages 26 - 46 ( 21 )

Abstract:


Aryl-aryl bond formation is one of the most important tools in modern organic synthesis. Therefore, there is a high level of interest to develop green, effective reaction system to obtain biaryls. This review summarized the recent advances in the metal-catalyzed Ullmann reaction in which the aryl-aryl bond was formed directly. Furthermore, different types of catalytic mechanisms, especially the surface reaction, have been summarized to help the design of the catalyst.

Keywords:

Aryl-aryl bond, biaryl skeletons, catalyst, graphene-based materials, metal-catalyzed synthesis, Ullman reaction.

Affiliation:

International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi 214122, International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi 214122, International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi 214122

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